Humans are usually exposed to arsenic compounds primarily through contaminated air, food, and water sources. The consumption of contaminated water for drinking is also an important source of arsenic exposure. Generally concentration of arsenic is usually higher in ground water than in surface water, especially when and where specific geochemical conditions favor dissolution of arsenic minerals.
Once arsenic compounds are ingested, the soluble forms of arsenic are readily absorbed from the gastrointestinal tract. The inorganic species i.e. As (V) and As (III) have different mechanisms of action on which their toxicity depends. Arsenate behaves similarly to phosphate. Consequently, they can substitute for phosphate in common cell reactions. The structural similarity of arsenates to phosphate allows them to substitute for phosphates in energy producing reactions. On the other hand arsenite have high affinity for the thiol group of proteins, causing inactivation of several enzymes.
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